Opis: Academia Publishing House of the Czechoslovak Academy of Sciences Praha 1977, str. 250 stan db (przykurzona , podniszczona lekko okładka, nieaktualne pieczątki) ISBN This book deals with phase equilibria solid-liquid and brings a detailed treatment of the solubilities of solids in liquid solutions. A characteristic feature of the book is that it contains, in addition to the classification and description of phase equilibria, also instructions for measurement and or estimation of solubilities. The chapter of the correlation of solubilities is unique in the world literature: it describes various methods scattered even in not easily accessible journals. Theoretical considerations and equations are illustrated by numerous examples and complemented by computer programs. Tables of solubilities are composed with the use of one of the correlation methods: the solubilities of threecomponent systems are tabulated in the form of constants of corresponding equations, what gives the possibility of easy temperature interpolations and even of estimation of solubilities in complex polycomponent systems. The book destined as a supplementary textbook for university students in chemistry and chemical engineering, for chemical engineers and technologists in chemical industries and related tranches, and for research workers in laboratories. CONTENTS List of symbols Introduction 1. Conditions for phase equilibrium 1.1. Single-component systems 1.2. Multicomponent systems 1.3. The Gibbs phase rule 2. Methods of expressing the composition of a system 2.1. Solutions and melts 2.2. Concentration units 2.3. Methods of graphical representation 2.3.1. Single-component systems 2.3.2. Two-component systems 2.3.3. Three-component systems 2.3.4. Four-component system 2.3.5. Multicomponent systems 2.3.6. The straight line rule and the lever rule 2.3.7. Enthalpy diagrams 3. Types of systems and their phase diagrams 3.1. Single-component systems 3.2. Two-component systems 3.3. Three-component systems 3.4. Four-component systems 4. Measurement of phase equilibria in condensed systems 4.1. Analytical methods 4.2. Synthetic methods 4.2.1. Polythermal methods 4.2.2. Isothermal methods 4.3. Dynamic method 4.3.1. Cooling curve 4.3.2. The kinetics of the growth and dissolution of crystals 5. Correlation methods for calculation of phase equilibria 5.1. Methods based on geometrical concepts 5.1.1. Orthogonal projection 5.1.2. Central projection 5.1.3. A modified method of central projection 5.1.4. Clinogonial projection 5.1.5. The symmetrical correlation method 5.2. Methods based on thermodynamic concepts 5.2.1. The method based on the electrolyte solution theory 5.2.2. The teory of eonformal ionic solution 5.2.3. The Zdanovskii method and modifications 5.2.4. Expansion of relative activity coefficients 6. Impurity inclusion in crystals 6.1. Isomorphous inclusion * 6.2. Adsorption inclusion 6.3. Formation of anomalous mixed crystals 6.4. The mechanism of internal adsorption 6.5. Mechanical inclusions 7. Literature 8. Tables of solubilities of various substances in water 9. Tables of solubilities in ternary systems (J. Nyvlt and J. Wiirzelova) Subject index
|